Just programmed a new key to a Chevrolet Matiz year 2013 using CK100 v45.06 (which is now update to v45.09) auto car key programmer within 2 minutes. VERY FAST!
Connect CK-100 with vehicle via main test cable
Select Immobilizer->Chevrolet-Daewoo->Matiz 06 up
Insert original key and turn on ignition
Select Program new keys
Insert new key and turn on ignition
Key programming success. Repeat to program more keys or cancel.
Save customer data.
Test the new key
The new key can start car.
Success.